The significance of Mn‐rich ilmenite and the determination of P–T paths from zoned garnet in metasedimentary rocks from the western Cape Breton Highlands,Nova Scotia     

Travis McCarron  Christopher R. M. McFarlane  Fred Gaidies 《Journal of Metamorphic Geology》2019,37(9):1171-1192

The Jumping Brook Metamorphic Suite in the western Cape Breton Highlands of Nova Scotia is part of an inverted Barrovian sequence that formed during a Late Silurian–Early Devonian promontory–promontory collision in the Canadian Appalachians. In this study, systematic discrepancies between geochemical observations and thermodynamic model predictions led to the discovery of a systematic relationship linking the style of garnet core isopleth intersection (GCII) to the pyrophanite (MnTiO₃) component of co‐existing ilmenite. Samples that yielded tight GCIIs at or near the garnet‐in curve were found to contain ilmenite with negligible pyrophanite components, whereas samples yielding GCIIs far removed (up to 105°C) from the garnet‐in curve were found to contain ilmenite with significant pyrophanite and/or ecandrewsite (ZnTiO₃) components. Based on petrographic and geochemical observations, Mn(±Zn)‐rich ilmenite are interpreted to have sequestered Mn throughout prograde metamorphism due to sluggish intracrystalline diffusion. The amount of reactive Mn input into the thermodynamic models from whole‐rock analyses were, in some cases, overestimated, resulting in garnet‐in curve topologies that extend to erroneously low P–T conditions. Modifications to the whole‐rock chemistry that account for Mn sequestration into ilmenite, however, yielded robust model results. Our results show that, in addition to uncertainties in thermodynamic data sets and phenomenon related to reaction kinetics, Mn‐rich ilmenite may superimpose additional complexities related to the interpretation of predicted equilibria involving garnet. Numerical simulations of garnet crystallization were used to infer P–T paths of metamorphism for one sample from the garnet zone (Mn corrected) and two samples from the staurolite zone (Mn uncorrected) of the inverted sequence. Model results are remarkably similar among the three samples and indicate that garnet crystallization occurred along relatively steep (31–37°C/km) clockwise P–T paths. The peak conditions of garnet crystallization and metamorphism (560–590°C, 7.4–8.0 kbar) are interpreted to have been attained approximately simultaneously, such that the paths are characterized by tight prograde‐to‐retrograde transitions. The hairpin nature of the P–T paths is interpreted to represent the onset of thrust‐related exhumation and isograd inversion along ductile shear zones, consistent with available field and geochronological constraints.  相似文献   

Depth to the apparent redox potential discontinuity (aRPD) as a parameter of interest in marine benthic habitat quality models     

Travis G. Gerwing  Kieran Cox  Alyssa M. Allen Gerwing  Charmaine N. Carr-Harris  Sarah E. Dudas  Francis Juanes 《国际泥沙研究》2018,33(2):149-156

The usefulness of the apparent redox potential discontinuity (aRPD) in assessments of marine benthic habitat quality was explored at two intertidal mudflats along the north Pacific coast of Canada. Two transects were established at each intertidal site, with three sediment biogeochemistry cores collected from each transect four times over the summer of 2016. Measurements of the sediment pore water dissolved oxygen (DO) content and redox (Eh) conditions were taken at the surface of the core (measured vertically), as well as at increasing depths (1 cm between readings) into the sediment (measured horizontally through predrilled holes in the biogeochemistry corer). While oxic, anoxic, oxidized, and reduced sediment pore water was observed above and below the aRPD, in general, sediment above the aRPD had higher DO content, and higher Eh values than sediment below the aRPD. Therefore, the aRPD depth can be used as a relative indicator of sediment pore water DO and Eh conditions: sediment with a deeper aRPD depth has more available DO, and the pore water has higher Eh values (more oxidized or less reduced) than sediment with a shallower aRPD depth. As such, the aRPD depth is a useful parameter to include in models that assess the quality of marine benthic habitats.  相似文献   

The anatomy of exhumed river-channel belts: Bedform to belt-scale river kinematics of the Ruby Ranch Member,Cretaceous Cedar Mountain Formation,Utah, USA     

Benjamin T. Cardenas  David Mohrig  Timothy A. Goudge  Cory M. Hughes  Joseph S. Levy  Travis Swanson  Jasmine Mason  Feifei Zhao 《Sedimentology》2020,67(7):3655-3682

Many published interpretations of ancient fluvial systems have relied on observations of extensive outcrops of thick successions. This paper, in contrast, demonstrates that a regional understanding of palaeoriver kinematics, depositional setting and sedimentation rates can be interpreted from local sedimentological measurements of bedform and barform strata. Dune and bar strata, channel planform geometry and bed topography are measured within exhumed fluvial strata exposed as ridges in the Ruby Ranch Member of the Cretaceous Cedar Mountain Formation, Utah, USA. The ridges are composed of lithified stacked channel belts, representing at least five or six re-occupations of a single-strand channel. Lateral sections reveal well-preserved barforms constructed of subaqueous dune cross-sets. The topography of palaeobarforms is preserved along the top surface of the outcrops. Comparisons of the channel-belt centreline to local palaeotransport directions indicate that channel planform geometry was preserved through the re-occupations, rather than being obscured by lateral migration. Rapid avulsions preserved the state of the active channel bed and its individual bars at the time of abandonment. Inferred minimum sedimentation durations for the preserved elements, inferred from cross-set thickness distributions and assumed bedform migration rates, vary within a belt from one to ten days. Using only these local sedimentological measurements, the depositional setting is interpreted as a fluvial megafan, given the similarity in river kinematics. This paper provides a systematic methodology for the future synthesis of vertical and planview data, including the drone-equipped 2020 Mars Rover mission, to exhumed fluvial and deltaic strata.  相似文献   

Hydrothermal dynamics in a CM‐based model of Ceres          下载免费PDF全文

B. J. Travis  P. A. Bland  W. C. Feldman  M. V. Sykes 《Meteoritics & planetary science》2018,53(9):2008-2032

A 2‐D numerical study of the evolution of Ceres from a “frozen mudball” to the present era emphasizes the importance of hydrothermal processes. Particulates released as the “frozen mudball” thaws settle to form a roughly 290 km radius core. Hydrothermal flow is driven by radiogenic heating and serpentinization. Both salt‐free and brine fluids are considered. Our modeling suggests that Ceres’s core has been warm over most of its history and is still above freezing, and convective processes are active in core and mantle to the present. The addition of low eutectic solutes greatly expands the region of active convection. A global muddy ocean persists for the first 3 Gyr, and at present, there may be several regional mud seas buried under a frozen crust. Transport of interior material to the near surface occurs throughout our model's history. Eutectic brines drive convective flow to near the surface, even breaching the surface in isolated regions, on the order of 30 km in width, similar in size to some mounds detected using the Dawn visible imaging camera (Sizemore et al. 2015). Surface features such as the bright spot in Occator crater and Ahuna Mons could be the result of eutectic plumes. The CM‐based model density profile is within 10% of Ermakov et al.'s ( 2017 ) results. The model mud mantle has a roughly 42:58 volumetric partitioning of H₂O to rock. Our mud model is consistent with the absence of large craters (Marchi et al. 2016 ) and an internal viscosity decreasing with depth (Fu et al. 2017 ).  相似文献   

International Pellet Watch: Global monitoring of persistent organic pollutants (POPs) in coastal waters. 1. Initial phase data on PCBs, DDTs, and HCHs   总被引：1，自引：0，他引：1  

Yuko Ogata  Kaoruko Mizukawa  Satoru Iwasa  Yukie Mato  Keiji Okuda  Michio Murakami  Ruchaya Booyatumanondo  Le Quang Dung  Carlos Miguez  Charles Moore  Steven Weerts  Erick Burres  Michael Van Velkenburg  Richard C. Lang  Brenda Danner  Richard C. Thompson 《Marine pollution bulletin》2009,58(10):1437-1446

Samples of polyethylene pellets were collected at 30 beaches from 17 countries and analyzed for organochlorine compounds. PCB concentrations in the pellets were highest on US coasts, followed by western Europe and Japan, and were lower in tropical Asia, southern Africa and Australia. This spatial pattern reflected regional differences in the usage of PCBs and was positively correlated with data from Mussel Watch, another monitoring approach. DDTs showed high concentrations on the US west coast and in Vietnam. In Vietnam, DDT was predominant over its metabolites (DDE and DDD), suggesting the principal source may be current usage of the pesticide for malaria control. High concentrations of pesticide HCHs were detected in the pellets from southern Africa, suggesting current usage of the pesticides in southern Africa. This study demonstrates the utility and feasibility of the International Pellet Watch approach to monitor POPs at a global scale.  相似文献   

Low pressure and desiccation effects on methanogens: Implications for life on Mars     

Timothy A. Kral  Travis S. Altheide  Adrienne E. Lueders  Andrew C. Schuerger 《Planetary and Space Science》2011,59(2-3):264-270

Conditions on the surface of Mars would appear to be too hostile for life as we know it. But the subsurface is another matter. If liquid water is present, even intermittently, life forms present would at least be protected from the lethal radiation bombarding the surface. However, life would have to contend with variations in pressure and possibly extended periods of desiccation. The research reported here involves both active metabolism (methanogenesis) at 400 and 50 mbar of pressure, pressures that would be found in the near subsurface of Mars, and survival following desiccation at both 1 bar (a pressure that would be found in the Martian subsurface) and 6 mbar (the lowest pressure at the surface and very near subsurface). The three methanogens tested for active metabolism, Methanothermobacter wolfeii, Methanosarcina barkeri and Methanobacterium formicicum, all demonstrated methane production at both 400 and 50 mbar on JSC Mars-1, a Mars soil simulant. Methane production at 50 mbar was much reduced compared to that at 400 mbar, most likely due to the greater stress at the lower pressure. In desiccation survival experiments, M. barkeri had survived 330 days of desiccation at 1 bar, while M. wolfeii and M. formicicum survived 180 and 120 days, respectively. Methanococcus maripaludis did not survive desiccation at all at 1 bar. At 6 mbar, M. wolfeii, M. barkeri and M. formicicum survived 120 days of desiccation while M. maripaludis survived 60 days. These results along with results from previous research would seem to indicate that there is no reason that methanogens could not inhabit the subsurface of Mars.  相似文献   

Corrigendum to “Decreased streamflow in semi-arid basins following drought-induced tree die-off: A counter-intuitive and indirect climate impact on hydrology” [J. Hydrol. 406 (3–4) (2011) 225–233]     

M. Guardiola-Claramonte  Peter A. Troch  David D. Breshears  Travis E. Huxman  Matthew B. Switanek  Matej Durcik  Neil S. Cobb 《Journal of Hydrology》2012

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Magnetic Evolution and the Disappearance of Sun-Like Activity Cycles     

Travis S. Metcalfe  Jennifer van Saders 《Solar physics》2017,292(9):126

After decades of effort, the solar activity cycle is exceptionally well characterized, but it remains poorly understood. Pioneering work at the Mount Wilson Observatory demonstrated that other Sun-like stars also show regular activity cycles, and suggested two possible relationships between the rotation rate and the length of the cycle. Neither of these relationships correctly describes the properties of the Sun, a peculiarity that demands explanation. Recent discoveries have started to shed light on this issue, suggesting that the Sun’s rotation rate and magnetic field are currently in a transitional phase that occurs in all middle-aged stars. Motivated by these developments, we identify the manifestation of this magnetic transition in the best available data on stellar cycles. We propose a reinterpretation of previously published observations to suggest that the solar cycle may be growing longer on stellar evolutionary timescales, and that the cycle might disappear sometime in the next 0.8?–?2.4 Gyr. Future tests of this hypothesis will come from ground-based activity monitoring of Kepler targets that span the magnetic transition, and from asteroseismology with the Transiting Exoplanet Survey Satellite (TESS) mission to determine precise masses and ages for bright stars with known cycles.  相似文献   

Can ensembles of regional climate model simulations improve results from sensitivity studies?     

Travis A. O��Brien  Lisa C. Sloan  Mark A. Snyder 《Climate Dynamics》2011,37(5-6):1111-1118

Intrinsic variability (IV) in regional climate models (RCMs) is often assumed to be small because at climatological timescales, the model solutions tend to be dominated by the model??s lateral boundary conditions. Recent studies have indicated that this IV may actually be large in certain instances for some variables. Direct interpretation of anomalies from RCM sensitivity studies relies on the assumption that differences between model simulations are entirely due to a physical forcing. However, if IV is as large or larger than the physical signal, then this assumption is violated. Using a 20 member ensemble of RCM simulations, we verify that IV of precipitation within a RCM can be large enough to violate the sensitivity study assumption, and we show that generating ensembles of simulations can help reduce the level of IV. We also present two indicators that can rule out the influence of IV when it is ambiguous whether anomalies within a sensitivity study are due to the sensitivity perturbation or whether they are due to IV.  相似文献   

Turbulent heat fluxes during an intense cold-air outbreak over the Kuroshio Extension Region: results from a high-resolution coupled atmosphere–ocean model     

Tommy G. Jensen  Timothy J. Campbell  Richard A. Allard  Richard Justin Small  Travis A. Smith 《Ocean Dynamics》2011,61(5):657-674

The coupled ocean atmosphere mesoscale prediction system that includes the Navy Coastal Ocean Model has been configured for the Kuroshio Extension region using multiple one-way nested high-resolution grids. The coupled model system was used to simulate a strong cold-air outbreak event from 31 Jan to 7 Feb 2005 in good agreement with meteorological data from a surface buoy data and QuikSCAT scatterometer winds. Latent heat fluxes and sensible heat fluxes were computed during the event with daily averages in excess of 1,500 W/m² and 500 W/m², respectively, and combined instantaneous turbulent heat fluxes up to 2,300 W/m². The largest heat fluxes were found in two large meanders of the Kuroshio and along its southern flank. Strong gradients in turbulent heat fluxes coincided with strong sea surface temperature gradients and were maintained during the cold-air outbreak simulation. The large turbulent heat fluxes lead to significant subtropical mode water formation during the event at a rate about 10 Sv in the cyclonic recirculation region south of the Kuroshio. This increased the volume of core layer mode water within the temperature range 16°C to 18°C by 10% and increased the surface area of that layer directly exposed to the atmosphere by a factor close to 5 in the model domain.  相似文献